All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. Alkali metal carbonates blending in MZO, X2CO3:MZO, control the band-gap, electrical properties, and thermal stability. Alkali metal sulphates are more soluble in water than alkaline earth metals. The carbonates of alkali metals are stable towards heat. It is li2Co3, as you can see carbonate is same in all only alkali metal is changing . For example, Li2CO3 +heat -> Li ­2 O +CO2 MgCO3 +Heat -> MgO +CO2 Na2CO3 +heat -> no effect. Thermal stability: * Carbonates are decomposed to carbon dioxide and oxide upon heating. However, carbonate of lithium, when heated, decomposes to form lithium oxide. The carbonates of alkaline earth metals also decompose on heating to form oxide and carbon dioxide. The solubility of carbonates increases down the group in alkali metals (except ) . But carbonates of alkaline earth metals are insoluble in water. The thermal stability of carbonates increases with the increasing basic strength of metal hydroxides on moving down the group.Thus the order is The bicarbonates of all the alkali metals are known. Compare the solubility and thermal stability of the following compounds of the alkali metals with those of the alkaline earth metals. Contrary to alkali metal sulphates, beryllium sulphate is water-soluble. All the bicarbonates (except which exits in solution) exist as solids and on heating form carbonates. 9:31 Ionic character and the thermal stability of the carbonates increases from Be to Ba. Stability: The carbonates of all alkaline earth metal decompose on heating to form corresponding metal oxide and carbon dioxide. This can therefore enhance the operational lifetime of QLEDs. Alkali metal carbonates, their thermal stability and solubility 5 What is the explanation of the changes in stability going down a group for carbonates, bicarbonates, fluorides, and chlorides? (a) Nitrates (b) Carbonates (c) Sulphates. Sulphates. The thermal stability of alkaline earth metal carbonates–MgCO3, CaCO3, SrCO3 and BaCO3, follows the order asked Apr 30, 2019 in Chemistry by RenuK ( 68.1k points) kvpy The smaller size and the charge density increases the hydration energy of the beryllium sulphate leading to more solubility. It describes and explains how the thermal stability of the compounds changes as you go down the Group. Solubility. Carbonates of metal: Thermal stability The carbonates of alkali metals except lithium carbonate are stable to heat. The effect of heat on the Group 2 carbonates. The carbonates of group-2 metals and that of lithium decompose on heating, forming an oxide and carbon dioxide . Whereas bicarbonates give carbonate, water and carbon dioxide. MCO 3 —-> MO + CO 2 The temperature of decomposition i.e. Thermal stability. 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Heat on the Group ­2 O +CO2 MgCO3 +heat - > Li ­2 +CO2...

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